Mine starts after the dogs are all fed and dinner is over. The streetclothes come off and my comfy nightshirt goes on. If I'm wearing my contacts, they come out and my hornrim glasses go on. I put on this really neat, luxurious foot cream and my special pink fuzzy socks of which I have about 7 or 8 pairs since I buy a new pair almost every time I go to Walmart. They are the softest socks I own. Then after brushing my teeth I come to the computer and settle in. I must put on lip balm! It's a rule. I have a nice array. Carmex, Cherry Carmex, Blistex, Badger, Aquafina Lip Oil, etc. I love lip lip balm and lip gloss. So I put on a few coats of that. Then comes the hand cream. Especially in winter. My hands dry out terribly in cold weather especially since I wash them so much and it's a constant fight to keep them moist. I have my favorite hand creams too. Depends on my mood. I have to have a nice diet cola on ice with a straw and my cell phone by me in case I get a call.
I have room sprays too that I will spray during my computer time. One is Walnut, there's also Pecan Caramel, Moonlight Path and Hazelnut. It used to be incense with me and I had about 50 kinds of incense but I switched to room spray. I prefer all the lights off except the stove light in the kitchen and my little gooseneck lamp here at my desk. I usually have my hair in a claw when I'm here.
If not at the computer, then my next favorite unwinding is to repeat the above (lip balm, fuzzy socks, hand cream) and crawl in bed with my latest good book. Books are a great escape. Sometimes a crossword puzzle book instead or that day's mail order catalogs.
I firmly believe in having rituals for things and that's my big comfort ritual for the evening.

What's yours??